Chapter 1 – Introducing Quantum Mechanics

Electrons as waves

Waves on a string give us insight into how an electron behaves as a wave.

A fixed length string only vibrates at certain frequencies – 1st harmonic, 2nd harmonic, …

There are two constraints on a electron orbiting an atom:

  • Electrons orbiting an atom are waves and the length of the orbit must be a multiple of the wavelength.
  • Changing the wavelength also changes the momentum of the electron. Each radius has a required momentum for the orbit to work

These constraints mean that only certain orbits are allowed.

Big Idea

Electrons as waves explains the fixed orbits and energy increments of electrons!